She's succeeded there. He's definitely intrigued by this woman who sees nothing wrong with coming onto his ship uninvited and getting straight to the point.

"Do you? Pray tell what is it?"

His crew appears a little more wary since they saw the woman just appear and he didn't. What if she's some type of Dark sorceress trying to trap their captain into a nefarious deal that involves all of them too?

For his part, Hook is willing to listen mostly because he still has a nagging suspicion that he already knows her.